The Helmholtz free energy of an ideal gas system is given by:

F = U - TS

where U is the internal energy of the system, T is the temperature and S is the entropy of the system.

Differentiating both sides with respect to the number of moles of gas (n) yields the following equation:

dF/dn = -T(dS/dn) + (U/dn)

Rearranging the above equation and substituting in the definition of the internal energy yields:

(U/dn) = -T(dS/dn) + (dF/dn)

Using the fact that the internal energy of an ideal gas is of the form U = nRT (where R is the gas constant) and the definition of entropy dS/dn = R ln(V/n), the above equation can be rearranged as follows:

RT = -TR ln(V/n) + (dF/dn)

Substituting in the definition of the Helmholtz free energy for a system of ideal gas (F = NkT ln(V/N) - PV) and rearranging, we obtain the ideal gas law for the system:

PV = RT

where P is the pressure of the system and V is its volume.